HEATS OF ASSOCIATION OF AQUEOUS COPPER, NICKEL, AND COBALT IONS WITH HALIDE IONS
- 15 July 1966
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 44 (14) , 1709-1716
- https://doi.org/10.1139/v66-256
Abstract
Calorimetric measurements are reported for the heats of formation of CoCl+, NiCl+, CuCl+, CoBr+, NiBr+, and CuBr+ from simple aqueous ions. Values of ΔF, ΔH, and ΔS for these reactions at 25 and 40 °C, and an ionic strength of 2.0 were found. It was noted that ΔH and ΔS seem to be related by the equation: ΔH = 254ΔS + 201, for values at both temperatures.Keywords
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