Reactivity of tetra-n-butylammonium di-µ-chloro-bis[bis(pentafluorophenyl)palladate(II)]. A general method for the synthesis of cis isomers of neutral and anionic palladium(II) complexes
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 463-465
- https://doi.org/10.1039/dt9810000463
Abstract
The reaction of [NBun 4]2[Pd2(µ-Cl)2(C6F5)4] with L (L = N, P, As, or Sb donor ligand) leads to the synthesis of novel anionic palladium complexes of the type [NBun 4][PdCl(C6F5)2L], which react with L to give the neutral complexes [Pd(C6F5)2L2]. Both families of compounds are the cis derivatives. Moreover, replacement of Cl by SCN or CN, and of L (SbPh3 or AsPh3) by PPh3, takes place without a change in configuration, giving again cis isomers.Keywords
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