Preparation and rearrangement of some conjugated phenylsulphinylacetate derivatives

Abstract
The direct condensation of saturated or un-saturated aldehydes with methyl phenylsulphinylacetate can be effected with the products undergoing base catalysed rearrangements those from saturated aldehydes yielding γ-hydroxy-αβ-unsaturated esters, whilst croton-aldehyde gives rise to methyl 6-phenylsulphinylhexa-2,4-dienoate.

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