Kinetics and mechanisms of unimolecular gas-phase γ-hydrogen rearrangements of aliphatic aldehydes at times of the order of 10 picoseconds and longer following field ionisation
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 836-837
- https://doi.org/10.1039/c39740000836
Abstract
Evidence is presented that the γ-hydrogen transfer in the decomposition processes of aliphatic aldehydes referred to as McLafferty rearrangement occurs as a discrete step at times longer than ca. 20ps following field ionisation.Keywords
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