Tetrahedral intermediates formed during the nucleophilic addition‐elimination reaction of carbonyl‐containing compounds in the gas phase. Part II
- 1 January 1988
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 107 (7-8) , 491-502
- https://doi.org/10.1002/recl.19881070704
Abstract
The structures of adduct ions formed between the nucleophiles HO− and CH3O− and various carbonyl compounds, such as aldehydes, esters and amides, have been probed in the gas phase by studying their proton affinity, collision‐induced dissociation pathways and chemical reactivity, using Fourier‐Transform Ion‐Cyclotron‐Resonance (FT‐ICR) Mass Spectrometry.Most of the generated adduct ions are shown to have stable, often proton‐bound, loosely associated structures as well as stable, covalently bound, tetrahedral structures.Keywords
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