Color Centers in Alkali Borate Glasses Containing Cobalt, Nickel, or Copper
- 1 January 1966
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 5 (1) , 85-94
- https://doi.org/10.1002/anie.196600851
Abstract
The absorption spectra and the magnetic moments of Co2+, Ni2+, and Cu2+ in alkali borate glasses of various compositions and in halide‐containing glasses have been explained from the point of view of the ligand field theory. Spectra and magnetic moments are highly dependent on the composition of the base glass; this must be ascribed to the change in the coordination of the transition‐metal ions. There are far‐reaching analogies with corresponding complexes in solution or in the crystalline state.Keywords
This publication has 32 references indexed in Scilit:
- Magnetische und optische Untersuchungen an nickelhaltigen AlkaliboratgläsernZeitschrift für anorganische und allgemeine Chemie, 1962
- The Electronic Structures of Tetrahedral Cobalt(II) ComplexesJournal of the American Chemical Society, 1961
- Electronic Spectra of Some Tetrahedral Nickel(II) ComplexesJournal of the American Chemical Society, 1961
- Magnetic Investigations of Spin-free Cobaltous Complexes. V. Tetra-azido and Tetracyanato Cobaltate(II) IonsJournal of the American Chemical Society, 1961
- Farbe und Konstitution bei anorganischen Feststoffen. II. Die Lichtabsorption des zweiwertigen Nickels in oxydischen KoordinationsgitternZeitschrift für anorganische und allgemeine Chemie, 1959
- Complete theory of Ni(II) and V(III) in cubic crystalline fieldsAnnals of Physics, 1959
- Optical Spectrum ofin the Cubic Crystalline Field of CaPhysical Review B, 1959
- Magnetic Properties of Spin-Free Transition Series ComplexesNature, 1958
- Valence Strength and the Magnetism of Complex SaltsThe Journal of Chemical Physics, 1935
- THE ATOMIC ARRANGEMENT IN GLASSJournal of the American Chemical Society, 1932