A new method of selective titanium silicide chemical vapor deposition for very shallow junctions is developed. This method includes an in situ silane cleaning treatment which greatly increases titanium silicide nuclei, and a silicon consumption control. Native oxide reduction from the silicon surface by the cleaning treatment is confirmed by secondary ion mass spectroscopy measurements. The dependence of the source‐gas flow rate on silicon consumption and film resistivity are clarified. The titanium silicide film properties are evaluated in conjunction with the silicon consumption. By applying thin titanium silicide films to test devices with 0.1‐μm‐deep shallow junctions, a low contact resistivity of around 10−7 Ω‐cm2 and a low leakage current of around 10−11 A/mm2 are obtained. The dependence of growth time on contact resistance and leakage current is also clarified.