3D Metal−Organic Frameworks Based on Elongated Tetracarboxylate Building Blocks for Hydrogen Storage
- 17 April 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 47 (10) , 3955-3957
- https://doi.org/10.1021/ic8003855
Abstract
Two 3D metal−organic frameworks (MOFs) with a new biphenol-derived tetracarboxylate linker and CuII and ZnII metal-connecting points were synthesized and characterized by single-crystal X-ray crystallographic studies. The two isostructural MOFs exhibit distorted PtS network topology and show markedly different framework stability. The porosity and hydrogen uptake of the frameworks were determined by gas adsorption experiments.Keywords
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