Fine structure in ‘metastable peak’ shapes in mass spectra

Abstract
The ‘metastable peak’ due to the collisioninduced reaction H3 +→ H++ H2 shows fine structure which probably arises because of the formation of H2 in several vibrational states while that due to H2 +˙→ H++ H˙ is composed of two separate peaks due to two different electronic transitions.

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