Interatomic interactions in metals
Open Access
- 1 January 1962
- journal article
- Published by EDP Sciences in Journal de Physique et le Radium
- Vol. 23 (10) , 643-647
- https://doi.org/10.1051/jphysrad:019620023010064301
Abstract
A theory of the cohesive properties of metals is developed which, though inapplicable to transition, rare earth, and actinide metals, holds otherwise for arbitrary composition and structure. The theory is based on two ingredients, a new dielectric formulation of the many-body problem and the pseudo-potential method for dealing with the ion cores. When the exact energy is expanded in powers of the pseudo-potential and the dominant terms retained, there results an approximate formula for the cohesive energy explicitly containing pairwise central forces between the atoms. It is proved that these forces are neither ionic nor covalent but specifically metallic in characterKeywords
This publication has 6 references indexed in Scilit:
- Dielectric Screening and Self-Consistent Crystal FieldsPhysical Review B, 1961
- Generalized Koopmans' TheoremPhysical Review B, 1961
- Cancellation of Kinetic and Potential Energy in Atoms, Molecules, and SolidsPhysical Review B, 1961
- New Method for Calculating Wave Functions in Crystals and MoleculesPhysical Review B, 1959
- Self-Consistent Field Approach to the Many-Electron ProblemPhysical Review B, 1959
- Correlation Energy of an Electron Gas at High DensityPhysical Review B, 1957