Synthesis and Reaction of 1- and 2-Methyl-1, 3-bis (trimethylsiloxy)-1,3-butadienes. Novel Dienes for the Diels-Alder Reaction
- 1 January 1977
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 7 (2) , 131-136
- https://doi.org/10.1080/00397917708050723
Abstract
The Diels-Alder reaction is one of the most widely employed methods is synthetic chemistry.1,2) The applicability of this reaction to the synthesis of useful cycloadducts is, however, rather limited.3) A recent communication from our laboratory described a synthetic method for new dienes: trans-1,3-bis(trimethylsiloxy)-5-methylcyclohexa-1,3-diene (2); and illustrated their potential usefulness in the synthesis of Neotropical frog toxin (3) via Diels-Alder cycloadducts.4)Keywords
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