Etudes sur les composés organométalliques I action du chlorure de benzylmagnésium et du bromure de phénylmagnésium sur le tétrachlorure de titane
- 1 January 1967
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 50 (4) , 1080-1084
- https://doi.org/10.1002/hlca.19670500414
Abstract
The reactions between phenylmagnesium bromide or benzylmagnesium chloride and titanium tetrachloride have been studied. The influence of the introduction order of the reagents is mentioned. Decomposition of the (non‐isolated) compounds RnTiX4‐n is shown to be essentially intermolecular, and rarely intramolecular.Keywords
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