Reaction field for efficient porphyrin metallation catalysis produced by self-assembly of a short DNA oligonucleotide

1 January 1998

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 15,p. 1533-1534
https://doi.org/10.1039/a801998c

Abstract

The G-wire structure, which is formed by dGTGGGTTGGGTGGGTTGG in the presence of 50 mM K⁺, becomes a catalytic reaction field for porphyrin metallation, inserting Zn²⁺ into porphyrin efficiently.

Keywords

STRUCTURE
PORPHYRIN METALLATION
PORPHYRIN EFFICIENTLY
DGTGGGTTGGGTGGGTTGG
WIRE
OLIGONUCLEOTIDE
ZN2

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