Regioselective and Stereospecific Synthesis of β,γ-Unsaturated Carboxylic Acids Using Allylbariums
- 1 January 1992
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1992 (07) , 593-594
- https://doi.org/10.1055/s-1992-21428
Abstract
Stereochemically homogeneous (E)- or (Z)-β,γ-unsaturated carboxylic acids were easily prepared in good yield by highly α-selective carboxylation of allylic barium reagents derived from the corresponding allylic chlorides with carbon dioxide.Keywords
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