Structural Dependence in a One-electron Transfer Process: Naphthalene peri Ketones
- 1 March 1980
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 53 (3) , 815-816
- https://doi.org/10.1246/bcsj.53.815
Abstract
The cyclic voltammetry of several naphthalene peri ketones was carried out in anhydrous DMF containing TBAP. The cathodic peak potential for carbonyl reduction was found to be shifted toward a more anodic potential when carbonyl, oxygen, and sulfur groups were present in the peri position. The controlled potential electrolysis of peri diketones gave an intramolecular coupling product via a bis-anion radical.This publication has 4 references indexed in Scilit:
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