Systematics of Core-Electron Exchange Splitting in3d-Group Transition-Metal Compounds

Exchange splittings of $3s$ electrons in $3d$-group transition-metal compounds have been obtained by x-ray photoemission spectroscopy. The data for the difluorides exhibit the expected dependence on $d$-shell spin and $s$-electron binding energy, and yield a $3s$ splitting of 2.6 eV/spin. Data on a series of manganese oxides clearly exhibit the effects of covalency.