13C Kinetic Isotope Effects for the Addition of Lithium Dibutylcuprate to Cyclohexenone. Reductive Elimination Is Rate-Determining
- 1 April 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 119 (14) , 3383-3384
- https://doi.org/10.1021/ja9636348
Abstract
No abstract availableThis publication has 16 references indexed in Scilit:
- The Mechanism of Organocuprate 1,4-Addition Reactions with .alpha.,.beta.-Unsaturated Ketones: Formation of Cuprate-Enone Complexes with Lithium DimethylcuprateJournal of the American Chemical Society, 1994
- New insight into the structure of organocuprate .pi.-complexes by determination of 13C,13C coupling constantsJournal of the American Chemical Society, 1994
- The role of trimethylsilyl chloride in Gilman cuprate 1,4-addition reactionsJournal of the American Chemical Society, 1993
- Stereochemical effects of trimethylsilyl chloride (TMSCl) on the conjugate addition of organocopper reagentsTetrahedron Letters, 1990
- New copper chemistry. 16. Mechanism of organocuprate conjugate addition: observation of cuprate-olefin complexes and lithium-coordinated intermediates in the reaction of lithium dimethylcuprate(I) with 10-methyl-.DELTA.1,9-2-octaloneJournal of the American Chemical Society, 1989
- Coordinattvely induced 1,4-diastereoselection in the reaction of acyclic α,β-enones with organocopper reagents. A new type of organocopper reagentTetrahedron, 1989
- An NMR investigation of the reaction between cinnamic acid esters and lithium dimethylcuprate. Initial formation of an olefin-copper π-complexJournal of Organometallic Chemistry, 1985
- Kinetics and mechanism of the conjugate addition of lithium dimethylcuprate to .alpha.,.beta.-unsaturated ketonesJournal of the American Chemical Society, 1981
- Reaction of lithium dimethylcuprate with (α-allenic carbonyl compounds: A 1,2-addition to the activated carbon—carbon double bond. Direct evidence for an α-cuprio ketone/copper enolate equilibriumJournal of Organometallic Chemistry, 1978
- Kinetic study of dimethyltrimethylene intermediates by the triplet mercury (63P1) photosensitization of dimetylcyclobutanonesJournal of the American Chemical Society, 1972