Enforced coordination of chromium(III) to a thioether donor in an encapsulated complex

Abstract
The synthesis, structure and preliminary spectroscopic and electrochemical properties of a hexadentate chromium(III) complex of a mixed sulfur–nitrogen containing ligand, with the 3-thia-6,10,13,16,19-pentaazabicyclo[6.6.6]icosane macrobicyclic structure, are reported.

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