The reaction of electrophilic terminal phosphinidene complexes with enolizable ketones: C–H vs O–H vs C–C insertion of phosphorus
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 16,p. 1903-1904
- https://doi.org/10.1039/cc9960001903
Abstract
Transient [PhP → W(CO)5], as generated from the appropriate 7-phosphanorbornadiene precursor, reacts at 120 °C with various enolizable ketones or β–diketones to give the products resulting from the insertion of phosphorus into either the α-CH, the enol OH, or the acyl-CH2 bonds.Keywords
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