Studies on Carbohydrates. IV. A Novel Highly Stereoselective Synthesis of 1-O-Acyl-β-D-glucopyranose Tetra-acetates via the Glucosyl Trifluoroacetate
- 1 April 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (7) , 943-948
- https://doi.org/10.1080/00397919008052796
Abstract
2,3,4,6-Tetra-acetyl-glucose (1) reacted with trifluoroacetic anhydride to give good yield of 2,3,4, 6-tetra-O-acetyl-1-α-O-trifluoroacetyl-α-D-glucopyranose (2) which was converted into corresponding 1-O-acyl-β-D-glucopyranose tetraacetates. β-Anomers of glycosyl esters were obtained by this method.Keywords
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