Synthesis and characterisation of stable anionic group 3a dichlorometallocene(III) complexes and the X-ray structure of [AsPh4][Nd{η-C5H3(SiMe3)2}2Cl2]
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 69-70
- https://doi.org/10.1039/c39830000069
Abstract
A new class of group 3a organometallic compounds, containing the dichlorometallocene(III) anion [Ln(cp″)2Cl2]– is reported, obtained most conveniently by Cl– addition to [{Ln(cp″)2Cl}2][cp″=η-C5H3(SiMe3)2]; the X-ray structure of [AsPh4][Nd(cp″)2Cl2] shows Nd–Clav. 2.668(4)Å and Cl–Nd–Cl 99.3(1)°.Keywords
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