Transformations of fac-Re(dmbpy)(CO)3(CO2H) in the presence of carbon dioxide (dmbpy=4,4′-dimethyl-2,2′-bipyridine)
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1411-1412
- https://doi.org/10.1039/a902453k
Abstract
Reactions of fac-Re(dmbpy)(CO)3(CO2H) 1 or fac, fac-Re(dmbpy)(CO)3(CO2)Re(dmbpy)(CO)3 2 with CO2, in DMSO or DMF containing small amounts of water, lead to the bicarbonato complex, fac-Re(dmbpy)(CO)3[OC(O)OH] 4; the formato complex, fac-Re(dmbpy)(CO)3(OCHO) 5, is not a major product in any of these reactions.Keywords
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