Kinetics of disproportionation–combination reactions between ethoxy-radicals and nitric oxide
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1673-1674
- https://doi.org/10.1039/j19680001673
Abstract
A minimum value of 0·2 has been obtained for the disproportionation–combination ratio for reaction of ethoxy-radicals with nitric oxide at 25°, the radicals being formed by the multiple addition of nitric oxide to ethyl radicals from the photolysis of diethyl ketone. Taken with earlier results at 95–200°, this gives a maximum activation energy for disproportionation of 0·8 kcal. mole–1, with the probability that the true value is indistinguishable from zero.Keywords
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