Photochemistry of halogenocarbon compounds. Part 4. Photochemical conversions of some fluorinated aza- and diaza-cyclohexadienes
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 3289-3291
- https://doi.org/10.1039/p19810003289
Abstract
Photoreaction of perfluoro-4-isopropyl-1-azacyclohexa-1,3-diene (1) gives a cyclobutene derivative (4), apparently via ring opening to an azatriene. Similarly, the perfluoro-di-isopropyldiazacyclohexa-1,4-dienes (7) and (10) undergo a retro [π4 +π2] process and, in one case, a diazatriene (11) was isolated. Conversions of some apparently similar systems did not occur.Keywords
This publication has 0 references indexed in Scilit: