Cobaloximes. Part 2. A modified Schrauzer synthesis for base-sensitive cobaloximes

Abstract
The generation of a cobaloxime(I) anion in dimethyl sulphoxide provides a clean, non-aqueous reagent of low basicity particularly useful for the synthesis of base-sensitive cobaloximes. The method has been applied to the synthesis of esters of (2,2-dicarboxypropyl)cobaloximes and their monothio-analogues.

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