Development of Palladium-Catalyzed Cycloalkenylation and its Application to Natural Product Synthesis
- 25 July 2002
- journal article
- account
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 2002 (8) , 1211-1222
- https://doi.org/10.1055/s-2002-32946
Abstract
To solve the drawback (considerable decrease in yield on a large scale) of cycloalkenylation employing stoichiometric amounts of Pd(OAc)2, a novel palladium-catalyzed cycloalkenylation has been developed. Stereoselective total syntheses of several bioactive terpenoids have been achieved by means of the above catalytic reaction.Keywords
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