Efficient coupling reactions of allylamines with soft nucleophiles using nickel-based catalysts
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1393-1394
- https://doi.org/10.1039/a702954c
Abstract
Substitution reactions of N,N-diethylallylamine 1 with soft nucleophiles such as active methylene compounds 2a–c and piperidine 5 proceed much more rapidly in the presence of Ni(dppb) 2 [dppb = 1,4-bis(diphenylphosphino)butane] as catalyst than with comparable palladium systems.Keywords
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