Reptation as a dynamic mean-field theory: Study of a simple model of rodlike polymers
- 14 June 1993
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 70 (24) , 3744-3747
- https://doi.org/10.1103/physrevlett.70.3744
Abstract
The simplest model of entangling polymers, a semidilute solution of hard infinitely thin rods that perform only translational Brownian motion, is studied. Reptationlike scaling theory for the transversal diffusion constant is presented. It is shown that the scaling predictions can also be derived from a microscopic dynamic theory in which the interaction of the pair of rods with the surrounding medium is described in a mean-field-like approximation.Keywords
This publication has 18 references indexed in Scilit:
- Mode-coupling theory of the dynamics of polymer liquids: Qualitative predictions for flexible chain and ring meltsThe Journal of Chemical Physics, 1989
- Microscopic theory of the dynamics of polymeric liquids: General formulation of a mode–mode-coupling approachThe Journal of Chemical Physics, 1989
- Generalized Rouse theory for entangled polymeric liquidsMacromolecules, 1988
- Tracer diffusion in polymeric mixturesMacromolecules, 1987
- Self-diffusion and reptation in semidilute polymer solutionsMacromolecules, 1986
- Molecular Theory on the Entanglement Effect of Rodlike PolymersPhysical Review Letters, 1985
- Dynamics of Semidilute Polymer Rods: An Alternative to CagesPhysical Review Letters, 1985
- Entanglements of Semidilute Polymer RodsPhysical Review Letters, 1985
- Dynamics of entangled polymersProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1983
- Reptation of a Polymer Chain in the Presence of Fixed ObstaclesThe Journal of Chemical Physics, 1971