Iridiumkomplexe des Vaska-Typs mit Triisopropylphosphan-Liganden [1]
Open Access
- 1 November 1984
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 39 (11) , 1505-1509
- https://doi.org/10.1515/znb-1984-1109
Abstract
The complexes trans-[IrClL(PiPr3)2] (L = CO , py, CH3CN) were prepared from [(C8H14)2lrCl]2 via[IrCl(PiPr3)2] as intermediate. rrans-[IrCl(CO)(PiPr3)2] reacts with LiC2Ph to form trans- [IrC2Ph(CO)(PiPr3)2] which on treatment with HX produces [IrH X(C2Ph)(CO)(PiPr3)2] (X = Cl, CF3CO2). The trifluoroacetate ligand is displaced by iodide to give [IrHI(C2Ph)(CO)(PiPr3)2]. trans-[IrCl(N2)(PiPr3)2] is obtained from the carbonyl complex and 2-furfurylazide.Keywords
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