A dinuclear rhodium–carbonyl cryptate of a ditopic macrocyclic ligand
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 296-298
- https://doi.org/10.1039/c39830000296
Abstract
Reaction of the ditopic hexa-aza-macrocycle (1) with tetracarbonyldichlorodirhodium(I) yields the dinuclears rhodium–carbonyl complex (1)–Rh2, which may be considered as a cryptate of triply bridged [Rh(CO)3Rh]2+ unit held inside the intramolecular cavity of the ligand.Keywords
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