Stepwise cluster synthesis via addition reactions of [OsH2(CO)4] and Na2[Os(CO)4]; the X-ray crystal structure of [Os7H2(CO)20]
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1373-1375
- https://doi.org/10.1039/c39820001373
Abstract
[OsH2(CO)4] and Na2[Os(CO)4] displace acetonitrile from Os3 cluster species to afford [Os4H2(CO)15],[Os4H2(CO)14(MeCN)], and [Os4H2(CO)13] whilst Os6 clusters afford [Os7H2(CO)21] and [Os7H2(CO)20] in high yields, thereby allowing the stepwise conversion of Osn into Osn+ 1 clusters; the structure of [Os7H2(CO)20] has been established by X-ray analysis.Keywords
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