Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with phenylacetylene; formation of mixed-valence Yb3(C5Me5)4(µ-CCPh)4and Eu2(C5Me5)2(µ-CCPh)2(tetrahydrofuran)4
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 710-712
- https://doi.org/10.1039/c39840000710
Abstract
Reaction of yb (C5Me5)2(OEt2) with PhCCH yields the mixed-valence complex Yb3(C5Me5)4(µ-CCPh)4 though Eu(C5Me5)2(OEt2) reacts with PhCCH to give the divalent complex Eu2(C5Me5)2(µ-CCPh)2(thf)4(thf = tetrahydrofuran)after crystallization from thf.Keywords
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