Further Results Concerning Half-Integral Hylleraas Expansions
- 1 May 1963
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 130 (3) , 1029-1032
- https://doi.org/10.1103/physrev.130.1029
Abstract
Previous calculations concerning the ground state of two-electron atoms, involving Ritz-Hylleraas expansions with half-integral powers, are continued through expansions involving 31 parameters. As far as can be judged from a comparison of the energies with those obtained with other expansions, the results continue to be favorable. Thus, already with 18 parameters, the computed energies for He and O vii differ from the best published values by 2 and 0.3 parts per million, respectively. Even better results are obtained for He with expansions involving both half-integral and negative powers. A few initial results of calculations for the excited state are also presented.
Keywords
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