Configurationally stable E–Z-aldonitrones
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 478-479
- https://doi.org/10.1039/c39740000478
Abstract
The elusive E-isomer of aldonitrones was formed in two independent kinetically controlled reactions; the observation of both the E- and the Z-aldonitrones at equilibrium, and their subsequent separation, permitted an estimation of rotational barriers by direct thermal stereomutation.Keywords
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