Activation of molecular oxygen by a metal complex. The formation and structure of the anion [Ph3POFe(S2C2{CF3}2)2]?

Abstract
Triphenylphosphine reacts with (Bu4N)2[Fe2(S2C2{CF3}2)4] in the presence of molecular oxygen to form a triphenylphosphine oxide adduct, (Bu4N)[Ph3POFe(S2C2{CF3}2)2], which had been previously formulated as a phosphine complex.

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