FACILE PHOTOGENERATION OF COORDINATTVELY UNSATURATED ACTIVE SPECIES FROM A HYDRIDOPHOSPHONITECOBALT(I) COMPLEX AND ITS APPLICATION TO DOUBLE-BOND MIGRATION OF OLEFIN
- 5 March 1983
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 12 (3) , 261-264
- https://doi.org/10.1246/cl.1983.261
Abstract
Pyrex-filtered irradiation of a thermally inert complex [CoH[PPh(OMe)2]4] dissociated PPh(OMe)2 from cobalt without cleavage of a hydrido–cobalt bond, yielding an active species “CoH[PPh(OMe)2]3”. The photogenerated species caused double-bond migration of 3-phenylpropene to (E)- and (Z)-1-phenylpropenes.This publication has 10 references indexed in Scilit:
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