A Simple Route to N-Acylaminophosphonoacetates (N-protected phosphonylglycine esters)
- 1 September 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (09) , 921-922
- https://doi.org/10.1055/s-1995-5126
Abstract
Rhodium(II) acetate catalysed reaction of triethyl diazophosphonoacetate 2 with amides, carbamates or ureas gives a range of N-acyl phosphonylglycine derivatives 3 by N-H insertion reaction of the intermediate rhodium carbenoid.Keywords
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