Isocyanide complexes of zerovalent ruthenium. Proton addition to a transition-metal base offering alternative base sites
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1271-1272
- https://doi.org/10.1039/c29710001271
Abstract
Ru(CO)2(CNR)(PPh3)2, Ru(CO)(CNR)(PPh3)3, and the dioxygen complex Ru(O2)(CO)(CNR)(PPh3)2, (R =p-tolyl) have been prepared by the action of bases on [RuH(CO)2(CNR)(PPh3)2]+ and [RuH(CO)(CNR)-(PPh3)3]+; protonation of Ru(CO)2(CNR)(PPh3)2 occurs specifically trans to isocyanide.Keywords
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