Stereoselective adsorption on a gold–thiol monolayer with an enantiopure surface
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 1199-1200
- https://doi.org/10.1039/c39940001199
Abstract
Self-assembled films of (+)-11-toluene-p-sulfinylundecanethiol on gold have been shown to adsorb the enantiomeric ethyl lactates from the gas phase; adsorption is totally unselective when the system is not in equilibrium during short exposures at 20 °C becomes totally selective after extended exposure at 40 °C.Keywords
This publication has 6 references indexed in Scilit:
- Chiral molecular recognition in monolayers of diastereomeric N-acylamino acid methyl esters at the air/water interfaceJournal of the American Chemical Society, 1992
- Chiral recognition of odorants (+)- and (-)-carvone by phospholipid monolayersJournal of the American Chemical Society, 1992
- Chiral Polypeptide Monolayers from Self-Condensation of Amphiphilic Amino Acid Ester. Effect of Chirality on the Membrane StructureChemistry Letters, 1991
- Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto goldJournal of the American Chemical Society, 1989
- Spontaneously organized molecular assemblies. 3. Preparation and properties of solution adsorbed monolayers of organic disulfides on gold surfacesJournal of the American Chemical Society, 1987
- Etude des melanges d'antipodes optiques—XIITetrahedron, 1976