Iodonium Ion Promoted Reactions at the Anomeric C-2 Center of 1-Methylene Sugars

Abstract
Treatment of fully benzylated 1-methylene-D-glucose with iodonium sym-dicollidine perchlorate (IDCP) gives and easy access to 1-iodoheptuloses or a 1-iodomethylene derivative, respectively. The latter compound is, in turn, further amenable to similar IDCP mediated addition reactions.

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