An aurophilicity-determined 3-D bimetallic coordination polymer: using [Au(CN)2]− to increase structural dimensionality through gold‥gold bonds in (tmeda)Cu[Au(CN)2]2
- 23 January 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 259-260
- https://doi.org/10.1039/b007342n
Abstract
A coordination polymer with the [Au(CN)2]− building block has been prepared and it exhibits weak Au(I)-mediated ferromagnetic interactions; the structure illustrates that aurophilicity is a powerful tool to increase dimensionality, generating a three-dimensional system from a 1-D polymer.Keywords
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