Ammonium acetate as a very simple and efficient cocatalyst for manganese porphyrin-catalysed oxygenation of hydrocarbons by hydrogen peroxide
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 1035-1036
- https://doi.org/10.1039/c39940001035
Abstract
A one-phase system using chloro[tetra(2,6-dichlorophenyl)porphyrinato]manganese(III) catalyst and ammonium acetate cocatalyst epoxidised alkenes by H2O2 with complete conversion in excellent yield and hydroxylated alkanes with yields of 45–87%; for most reactions this system gave better results than a previously described analogous system using imidazole cocatalyst.Keywords
This publication has 0 references indexed in Scilit: