A Mössbauer study of organotellurium compounds. Part I
Open Access
- 15 October 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (20) , 3234-3241
- https://doi.org/10.1139/v76-462
Abstract
Mössbauer data for a wide range of organotellurium compounds are reported, including compounds of the type: R2Te, Ar2Te, Ar2Te2, R2TeX2, Ar2TeX2, and ArTeX3; where R = alkyl, Ar = aryl, and X = Cl, Br, or I. The isomer shifts and quadrupole splittings are interpreted in terms of the relative populations of the tellurium 5s and 5p orbitals. The quadrupole splittings are rationalized in terms of a simple additive model, formulated within the framework of the Townes and Dailey theory.Keywords
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