Halogenated alkyl radicals
- 1 January 1973
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 25 (1) , 225-236
- https://doi.org/10.1080/00268977300100211
Abstract
The E.S.R. spectra of the β-fluoroisopropyl radical and the β-fluoro, β,β-difluoro and β,β,β-trifluoroethyl radicals have been recorded in fluid solutions. The conformational preferences and barriers to internal rotation in these species have been determined from an investigation of the temperature dependence of the β-fluorine and β-proton hyperfine coupling constants. The experimental hyperfine splittings have been compared with theoretical values calculated by the INDO method.Keywords
This publication has 21 references indexed in Scilit:
- A comparative study of some oxygen and sulphur substituted alkyl radicalsTetrahedron, 1972
- Electron spin resonance studies of conformations and hindered internal rotation in transient free radicalsThe Journal of Physical Chemistry, 1971
- Structure of ketyl radicals. II Electron spin resonance study of spin delocalization into perfluorinated alkyl side chainsJournal of the American Chemical Society, 1971
- An electron resonance study of some reactions involving silyl radicalsJournal of the Chemical Society B: Physical Organic, 1971
- A theoretical analysis of the temperature dependence of the E.P.R. spectrum ofbis(trifluoromethyl) nitroxideMolecular Physics, 1970
- Hyperfine coupling constants of the 2-chloroethyl and related radicalsChemical Physics Letters, 1970
- Conformation and Structure as Studied by Electron Spin Resonance SpectroscopyPublished by Wiley ,1967
- Anomalous Temperature Dependence in the Electron Spin Resonance Spectrum of Bis(trifluoromethyl) Nitroxide1Journal of the American Chemical Society, 1966
- ALIPHATIC FLUORIDES. II. 1-HALOGENO-ι-FLUOROALKANES1The Journal of Organic Chemistry, 1950
- Fluorinated Derivatives of Ethane and Ethylene. VIIJournal of the American Chemical Society, 1948