Synthesis and X-ray crystal and molecular structure of the mixed-metal cluster anion[Os6Au(CO)20H2]?
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 753-755
- https://doi.org/10.1039/c39810000753
Abstract
The unsaturated mixed-metal cluster anion [Os6Au(CO)20H2]– has been prepared as its [N(PPh3)2]+ salt by the reaction of [Os3Au(CO)10(PR3)H](R = Ph, Et) with [N(PPh3)2]Cl; its X-ray crystal structure shows that the AuI atom links two ‘Os3(CO)10H’ units via co-ordination to two short Os–Os bonds.Keywords
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