Stereospecific synthesis of carbocyclic analogue of oxazinomycin by retrograde aldol C–C bond fission under reductive conditions
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1422-1423
- https://doi.org/10.1039/c39870001422
Abstract
The Diels–Alder adduct prepared from cyclopentadiene and methyl (E)-3-acetoxy-2-cyanoacrylate (a newly synthesized dienophile) can be converted stereospecifically into the title compound using a retrograde aldol reaction under reductive conditions as a key step.Keywords
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