Lamb shift measurement in the1t1S ground state of helium

Abstract
With a phase-modulated extreme ultraviolet pulsed laser source the frequency of the 11S-21P transition of helium at 58 nm has been measured. The phase modulation scheme enabled measurement and reduction of frequency chirp, usually limiting pulsed precision spectroscopy. From the measured transition frequency of 5 130 495 083(45) MHz, a fourfold improved value of the ground state Lamb shift of 41 224(45) MHz is deduced, in good agreement with a theoretical value of 41 233(35) MHz based on QED calculations up to order α5 Z6. From these measurements, the well-known binding energy of the 21P state and the previously determined 34He isotope shift, accurate values for the ionization energies of the helium atom follow: 198 310.6672(15)fcm1 for He4 and 198 301.8808(15)fcm1 for He3.