Preparation of pure optically active (3s)‐ and (4s)‐tert‐butylcyclohexenes
- 1 January 1980
- journal article
- research article
- Published by Wiley in Bulletin des Sociétés Chimiques Belges
- Vol. 89 (8) , 637-642
- https://doi.org/10.1002/bscb.19800890806
Abstract
(1S, 3S) ‐3‐tert‐Butylcyclohexanol, obtained from enzymatic reduction of racemic 3‐tert‐butylcyclohexanone, is dehydrated to optically active cyclohexenes. The carbon‐13 NMR spectral data and ORD‐curves are given. The optical rotation of the (3S)−(+) and (4S) − (−) −tert‐butylcyclohexene are interpreted in terms of ring dissymetry.Keywords
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