Spectrophotometric Determination of Lead by Extraction of the Mixed-Metal Complex Pb(II)-Ca-Purpurin (1,2,4-Trihydroxyanthraquinone)
- 1 June 1994
- journal article
- research article
- Published by Taylor & Francis in Analytical Letters
- Vol. 27 (8) , 1595-1611
- https://doi.org/10.1080/00032719408006392
Abstract
Mixtures of Lead(II) and Ca(II) form with purpurin (P; 1,2,4-Trihydroxyanthraquinone) the mixed-metal-complex PbCaP3, which is extracted with isobutyl methyl ketone (IBMK) at pH 7.8. The molar absorptivity of the complex is 2.8 × 104 l.mol−1.cm−1 at 575 nm and its conditional extraction constant 2.5 × 1017 14.mole−4. The use of this complex for the spectrophotometric determination of lead up to 40 μg has been investigated. The proposed procedure has been successfully applied to the analysis of this metal in different samples.Keywords
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