STÉROÏDES: CCXIX PREPARATION ET PROPRIÉTÉS DE QUELQUES 17-ISO-PREGNANES ET 17-ISO-PREGNÈNES SUBSTITUÉS EN C-16
- 1 January 1963
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (1) , 156-164
- https://doi.org/10.1139/v63-020
Abstract
The preparation of 16β-carboxy-(5α)-17α-pregnane-3β-ol-20-one and 16β-carbomethoxy-3β-fluoro-17α-Δ5-pregnene-20-one, as well as several of their derivatives, is described. The stereochemistry of these compounds is deduced from their optical rotatory dispersion curves.Keywords
This publication has 9 references indexed in Scilit:
- Steroids. CLXXXVIII.1 New Fluorination Procedures. Part 3.2 cis-Addition of Fluorine to a Steroid Olefin. A New Route to 6α-Fluoro-Δ4-3-ketones3Journal of the American Chemical Society, 1962
- The addition of hydrocyanic acid to Δ16-pregnen-20-onesTetrahedron, 1958
- The Reaction of Epoxides with Anhydrous Hydrogen Fluoride in the Presence of Organic Bases. The Preparation of 9α-Fluoro-4-pregnene-11β,17α,21-Triol 3,20-Dione 21-Acetate and Its 1-Dehydro AnalogJournal of the American Chemical Society, 1956
- STEROLS. XIV. REDUCTION OF EPOXY KETONES BY CHROMOUS SALTS1The Journal of Organic Chemistry, 1954
- The Action of Alcoholic Potassium Hydroxide on ▵16-20-Ketosteroids1Journal of the American Chemical Society, 1951
- Preparation, Structure and Configuration of Some Salts Derived from Δ6-i-Cholestadiene and i-Cholesten-6-one1aJournal of the American Chemical Society, 1948
- Über Steroide und Sexualhormone. (136. Mitteilung). Synthese von 14‐Oxy‐Steroiden II; Verbindungen der Allo‐pregnanolon‐ReiheHelvetica Chimica Acta, 1947
- Sterols. CXXXII. Sapogenins. LIV. The Action of Hydrogen Peroxide on the Pseudosapogenin Acetates and on the PregnenolonesJournal of the American Chemical Society, 1942
- Eine neue Darstellungsweise von Cholesterinäthern.Hoppe-Seyler´s Zeitschrift Für Physiologische Chemie, 1932